Its a good item to deal with if you shoot C&B (Or C&Conical).
The bussniess about proving a negative plays in, grease or wax or ..... over the mouth and never a chain fire. But the same number of shots were not fired with none of that.
Its a bit like throwing the Maiden in the Volcano and it quit, ok, we threw in a man before and it did not so the answer is the Maiden.
I have only shot maybe 500 rounds of C&B (and a few C&C) - I was turned off in the 70s on C&B (no C&C then ) because of the so called Crisco requirement. Mawg, what a mess.
I have related my wife gave me her ASP 58 NMA some years back and last year I could not stand it and rigged up to shoot it. I reviewed the chain fire thing and concluded it was a myth.
1. They did not grease chambers back in the C&C/C&B days.
2. I saw the testing and they could reliably induce a chain fire under .451 (they would not say what but the .451 was the do not go over this line and it may be iffy even there)
I have not had any chain fires. Shot 5 different BP revolvers now. Mostly .454 or .457. If I do .451 I put a lubed felt wad behind the bullet (and have done it in front of bullets).
Its clear if you do one in front of a bullet the blast pattern does not penetrate more than the front surface, it looks to be a dandy flame arrester (ergo stop or assist in stop of chain fire)
Concur that you want a slightly oversized ball that will leave a shaved ring on the cylinder mouth. That (in theory) should seal the cylinder mouth (if the ball was solid and had no cavities and assuming the chamber is smooth and without gaps).
I would amend that to you want a chamber that squeezes the ball and creates a band such that it seals. My ASP has tapered chambers, no lead ring but it squeezes a good band at .454.
Oval chamber or one with a flaw can of course leave a gap and grease over the top or a lubed felt wad may well do the seal.
As for rear chain fire. I don't discount it but I do believe is truly odd circumstances that might cause it. As was noted, fire wise you would have to change directions no less than twice at 90 deg (so each time less and less fire) and then down a small hole, into an even smaller hole and set off enough grains of powder to start igniting. Sometimes getting ignition is hard enough with a cap on a Cone firing right. I have had to loosen up a few loads to get them to go off.
As you can't put grease over the Cone, yet to see what can be done about it.
The situation with Caps and the questions abut them are good ones. Sometimes we only can get 11s, RSW1175 seem to fit a lot better and then what was the variance of caps originally and were they better than what we have now?
No one has an answer to that I have seen.
You can check your chamber seal by seating a ball of conical and then pushing it out with a punch with the Cone removed and see how each chamber does.
While I play with .451 a bit just to see about accuracy I do it with treated wads.