An Overcharge doesn't make a rifle unsafe to fire, does it?
What do you think a proof load is????
As others have stated, "safe" or not depends on specifically what the overcharge was and the individual rifle it happened in.
I know of a Remington rifle (.308Win) that got fired with about a half case full of pistol powder. Case rupture, vented gas, some small parts broken, too a gunsmith to open the action and remove the ruptured brass.
Indications were it survived 90-110,000 psi. Rifle was repaired and returned to use, and has been fine for over 40 years since.
A different rifle model might not have fared so well.
Remember that the listed MAX loads are NOT max loads for blow up safety, they are the safe max WORKING loads with the particular combination of gun and ammo components tested.