Very interesting observation, and not one I've ever heard anyone else make!
I first made it in a gun shop years ago when I heard a guy behind the counter talking about bullets yawing as they jumped the gap and simply pointed out that the cylinder face is only about .006-.008 inch from the barrel face.
From his blank expression, I knew that he wasn't getting it...so, I grabbed a jacketed 158 grain .357 bullet from one of those loose zip-lock bags in the store and dropped it into the barrel of a revolver...then swung the cylinder to show how much bullet would remain in the throat. With that particular combination, the bullet is actually starting to engage the rifling before the base clears the case mouth.
Incidentally...for best accuracy with any bullet and less fouling with lead bullets...an unfired bullet dropped into a chamber should stick in the throat, and push through with light to moderate force, depending on whether it's jacketed or lead...lead bullets being typically .001 inch larger than nominal diameter.
So, "yawing" can't happen. The bullet is guided straight into the barrel from the instant it moves until it leaves the muzzle...first by the case, then the throat...and finally the taper in the forcing cone takes care of any slight cylinder to barrel misalignment long before the bullet base reaches the gap.
Sometimes the answer to a question has been staring us in the face the whole time. We only have to take the time to look.