It is all in the PHysics but
The physics relate more to the MASS of the bullet than the mass of the powder.
Regarding the volume of the different cases consider Boyle's law which states that in a perfect closed system containing a gas, the volume and pressure will react inversely. That means the 30-06 case which has a larger volume so will have less a lower pressure.
If all the science is confusing do you test this way. Vary the powder charge with the same weight bullet in the same case. Then you will see increased recoil with a higher powder charge. Another alternative test is to shoot 2 different bullet weights with the same powder charge out of the same case and you will find that the lighter bullet will recoil less. If you do both tests, you will notice LESS difference between the varied powder charges than between the varied bullet weights.
The physics relate more to the MASS of the bullet than the mass of the powder.
Regarding the volume of the different cases consider Boyle's law which states that in a perfect closed system containing a gas, the volume and pressure will react inversely. That means the 30-06 case which has a larger volume so will have less a lower pressure.
If all the science is confusing do you test this way. Vary the powder charge with the same weight bullet in the same case. Then you will see increased recoil with a higher powder charge. Another alternative test is to shoot 2 different bullet weights with the same powder charge out of the same case and you will find that the lighter bullet will recoil less. If you do both tests, you will notice LESS difference between the varied powder charges than between the varied bullet weights.