I wouldn't use it--if that's what you're thinking. Don't know what or why it's like that. My only guess is something to do with full-length sizing die or seat die compressing the shoulder?
Could it be a mark left by an improperly set neck sizer? Or someone treid to use a sizer die from a different caliber on it? Lube it and run it through a full length sizer and see if the ring is still there.