No. I haven't looked at a Webley chamber, but in a typical revolver that would jam the throat and prevent chambering. That's how 44 Magnum cartidges are prevented from chambering in a 44 Special by mistake. They make the Magnum case 1/8" longer. The overall length of the two cartridges is the same (well, OK, the older 44 Special is actually 0.005" longer, but that's not significant). But that's all it takes to ensure the higher pressure magnum round can't be accidentally fired in a Special chamber.
If I look up the Webley in QuickLOAD it says the .455 Mark I case is 0.886" long, while the .455 Mark II case is 0.767" long. I expect that's what you are seeing; the difference between the Mark I and Mark II cartridge designs. Whey they shortened it, I don't know. Probably for lighter revolvers as the peak pressure for the Mark II is 25% lower as well (1200 bar for the Mark I, or about 17,400 psi, vs 900 bar for the Mark II, or about 13,000 psi.