Boy we're a cheapie bunch.
Er, I mean not prone to wastefulness.
The only powder I can remember disposing of had been out in an unattached building for quite a few years, only about a quarter full.
It smelled suspicious, too, kind of vinegary.
When a very small amount was lighted, it burned funny.
That might be an easy way to check.
(notice the emphasis on "very small amount")
A couple of my not often used powders, in 1 lb containers, are nearly twenty years old and are still just fine.