Usually a SS barrel should shoot around 3500 rounds. Chrome-moly runs around 3000. You can gain about 20% (go to almost 4000 rounds) in SS by having it cryo treated (and I believe John Kreiger is cryo treating his barrels). I have seen claims that Chrome-moly responds more dramatically to cryo treating than SS and will have its life extended even more, but Mete says there isn't solid literature to support this. Worth a try, in my view.
It bothers me that you get good groups sometimes and not others. Three more things to mess with:
First, you are correct that self-loading can affect a cartridge. If you have a concentricity gage, measure the runnout on a half a dozen bullets right out of the Redding seating die. You will find they are very good. Next time you are at the range, load the magazine and shoot, manually ejecting and catching every other live round in your hand. When you get home, measure the runnout on the ejected rounds. If it is like my M1A, you will find a number of the bullets have been tipped in their case necks significantly.
Also, while you are shooting, fire some single-loaded groups for comparison. In service rifle matches the 600 yard slow fire phase is always singly loaded and that is the only way it is safe to use the thinner turned necks. Try going through finding a seating depth sweet spot as I described, just for single loading.
Second, years ago pistol competitors noticed that military match ammo would outshoot commercial match made by the same company using the same components. It turned out to be due to the pitch used to seal the bullets in the case. It sticks just enough to increase the start pressure and makes that start pressure more consistent. This leads to a couple of things you can do about start pressure: get a Redding sizing die with the interchangeable neck bushings so you can try a tighter neck; get a Lee factory crimp die and see how it does with your bullets? You need to concern yourself with the age of the brass because it gets more springy as it work hardens with age, tending not to neck down quite as far as it did originally. Neck annealing can fix this, but you see a lot of arguments about the effectiveness of home annealing methods and tools.
A third possibility is that you are getting a secondary pressure spike. These can be dramatic and inconsistent, and the .223 has been known to get them, even with some factory ammo. This phenomenon occurs mainly with the light, fast bullets propelled by slow double-base powders. Charlie Sisk has actually blown up a number of barrel muzzles with secondary pressure spikes and without any pressure signs appearing on the case. It seems to be a high brissance detonation near the base of the bullet as it's about to exit the muzzlem and only seems to occur starting at nearly 20" down a barrel. If you were getting this problem, it might well be inconsistent and cause fliers. The cure is either to move to heavier bullets or go to a faster single-base stick powder. To learn more about it, read
this and
this.
Nick