A pure lead egg sinker, a brass rod and a HEAVY (5# hammer) because the quick impulse of a small hammer blow can stick the sinker into the barrel. The brass rod needs a point at the end to sink into the sinker thus centering it.
The S&W barels are 5 grooves and are a bit more difficult to get an accurate measurement from. Also, you should remove your cylinder and slug each chamber...I have a Ruger that had one chamber that was tighter than the barrel. It would swage down ALL diameter lead bullets to the point it always leaded the barrel...until I had it reamed out.
An easier way to do this is order bullets of each diameter and see if any one diameter fires best and leads the least. Any commercially cast bullet, I give them a quick tumble lube in a mix of lee liquid alox/johnsons paste wax and just a bit of mineral oil....this has helped a lot in virtually eliminating leading at all pistol velocities...right up to gas checked bullets pushed to 1400fps.