I had an HK 91 (back in the 80s)
And my experience was that, for a battle rifle, the are somewhat sensitive to the ammo used.
2- The combustion gases escaping to the chamber help to "float" the brass somewhat, aiding in extraction.
The HK 91 is probably best described as a delayed (or retarded) blowback. It is often called a "roller locked" action, but in reality it does not actually "lock" in the same sense as other rifles. It is the combination of the roller lock and the fluted chamber that keeps the bolt closed until the pressure has dropped. The fluted chamber is not for debris clearance, or to aid extraction, it is so that the case "sticks" in the chamber longer, so that the pressure will drop before the bolt extracts it. Cases come out dirty, and fluted, and very hot. The the residual gas venting down the flutes does aid in extraction, literally blowing the case out of the chamber, which, because there is no camming action from the bolt head is probably a needed thing. But the main purpose of the fluted chamber is to retain a grip on the case longer than what happens in a non fluted chamber.
For this to work correctly, the case must be of the "proper" hardness. Too soft or too hard and it will not work right. This doesn't matter nearly as much in a rifle like the FAL or the M1A, but in an HK (or clone) it does. German made ammo works excellent. US GI ammo is often too "soft", and can give trouble, as the "soft" brass grips the fluted chamber too well and does not release at the proper time for best functioning. When the HKs first came to the US, lots of guys found them to be jamm-o-matics when using USGI surplus ammo. A quick field fix for this is a light shot of oil to the loaded magazine. The oil reduces the grip of the brass in the chamber and the rifles worked. However, this fix is only for use just before firing, as leaving the ammo oiled in the mag is not a good idea, as oil will kill primers. GI ammo
should be proof against this, because it is sealed, but sometimes it is less than perfect. And the oiled ammo picks up dust and grit if exposed to the environment, which is not a good thing to put into your chamber.
I can't say if the South african ammo is any good or not, I have not used any, sorry. Clean your gun, try some other ammo, and see how it behaves.
The scope mount was mentioned, and
might be a problem. Take your rifle down, and with the spring out work the bolt back and forth (after cleaning), if any drag is felt, remove the scope mount and try again. IF it still binds, you might need the services of a professional to see if the reciever has been damaged.
Good luck, and let us know how it goes.