What is the difference between regular large rifle primers and match primers?
Consistency.
CCI Benchrest primers:
In benchrest competition, there’s no such thing as a group that’s “too small.” Everything has to be tuned to the highest degree to produce match-winning results. That’s why we make CCI Benchrest primers. Only our most experienced skilled personnel put the priming mix in the cups, so you get the same flame, shot after shot. We also use specially selected cups and anvils for added consistency. An independent researcher identified the use of CCI Benchrest primers as one of two factors that were the most significant contributors to tiny groups. We can’t add much to that!
http://www.cci-ammunition.com/products/primers/primers.aspx?id=27
This article is worth reading as it is an excellent primer, on primers.
Mysteries And Misconceptions Of The All-Important Primer
http://www.shootingtimes.com/ammo/ammunition_st_mamotaip_200909/
I had a bud who worked with the ammunition industry. Manufacturers have instrumented “mules” that measure every primer characteristic you could ever dream of. Things like mass ejected, flame temperature, duration, gas volume, etc, etc. He told me that workers on the production line are given cash awards if their primer mix is the most consistent on the mule. A further interesting part of the discussion was that the most consistent primer cake is an “artifact”, that is, who makes it varies, and no one always makes the most consistent primer cake.
I recall reading that CCI weighed their benchrest primers along with lot testing.
Most competitive shooters I know use CCI benchrest, but there is a smattering who use Russian primers (which are really good) and Federal Match. Based on my reading, CCI benchrest may have a dedicated line, Federal Match comes off the same production line as standard, but is sorted out by lot consistency.
I conducted a primer test, where I held the bullet, cases, charge all the same and varied the primers, and I saw differences between the groups. The results could have been shuffled if I then proceeded to play with bullet seating depth, charge weight, etc. The home reloader just does not have the instrumentation to directly measure primer characteristics and consistency, and that any errors attributable to primers is buried by the huge errors people have in aiming and shooting.
There are differences between match/standard primers and mil spec primers. You will find that standard primers are more sensitive than mil spec primers. Military weapons tend to have heavy, free floating firing pins, and the kinetic energy of a firing pin rebounding off a primer will cause ignition if the primer is sensitive enough to ignite. For that reason mil spec primers are less sensitive on the average than commercial primers. Military weapons also tend to have robust ignition systems which reliably ignite mil spec primers. Many commercial firearms are a disappointment in this regard, their ignition systems are infact weak, and they will misfire if mil spec primers are used in them.