The cylinder bolt should drop into its' notch just before the sear sets. Same thing for DA - the cylinder bolt should lock just before the hammer is released. If your cylinder is locked each time, as you cycle through your test, then you need a gunsmith
I have played around with my 4 S&Ws for some time now trying to identify whether or not they have a decent timing on them, only 2 of them are what I consider to be perfect and it's not surprising to me because they are the ones in the closest to "new" condition that I have.
Hopefully I can explain what the 2 guns are doing so that it's easy enough to understand.
My 2 guns that I know need a timing job, fall on both sides of the "you need a gunsmith" suggestion. My oldest gun, a postwar 38/44 has still got relatively good timing in that on 4 out of the 6 chambers the bolt will lock up just as the hammer sets for single action pulls, with a finger lightly dragging on the cylinder 2 of the chambers will not rotate entirely into position and lock when the hammer sets. However, when you pull the trigger the chambers will both rotate into position with the additional reward travel. On double action, all 6 chambers will lock up just before the hammer falls. For a 40-50+ year old gun, it's held up pretty darned well.
The other gun that I am 100% certain needs a timing job, is my Model 29. From the discription given, it sounds like the cylinder stop is engaging way too early in the trigger pull for single action or while setting the hammer for a single action pull. I would assume the hand is a bit too long which is what causes it to do this, does having a revolver that locks up it's cylinder too soon cause accelerated wear or why exactly is it a bad condition?
On a whole, the 29 needs work, it's got a bit of end shake, doesn't have what I consider to be perfect alignment of the chambers/barrel, and the timing seems to be a bit off. If the end shake is fixed, I'm hoping that the chamber/barrel alignment will be brought under control.
For not having gotten a Kuhnhausen manual yet, I feel my understanding of how the things work is pretty good. I'm smart enough to not have done anything
major with the gun's actions, aside from having them totally apart on a few occasions to clean up some unexplainable grit in the actions that came from the factory guns. Once I finally get the Kuhnhausen manual for the S&W guns, I might be tempted to do the simpler stuff on my own.