You should be able to take a flashlight and shine it into the muzzle of your rifle barrel. Copper streaks would show up there. That said, I'm pretty sure you are going to see exactly that, but the copper streaks don't necessarily indicate that you have TOO much copper.
I would say that if you've run a lot of bullets down your barrel over time, and that standard cleaning (Butch's Bore Shine for instance) doesn't bring your accuracy back to where it was or should be, then maybe it's time to take some copper out. For that purpose I use Boretech Eliminator, though there are other choices out there. I've gotten away from the ammonia based copper removers, since I don't think that they are very effective. For example, when I got that first bottle of Boretech, I cleaned the barrel of a rifle that already had a clean barrel (or so I thought). I found that I had a lot of copper in a barrel that I had thought was clean.
Just to say it, my thinking on copper now is that I want some copper in the barrel of most of my rifles for best accuracy, so I don't clean with Boretech every time.