It's easy to measure. Take a piece of wire and look down the chamber. You'll see the step where the end of the chamber enters the forcing cone. Hold one end of the wire against that step and mark it where it come out of the chamber. Measure that length.
Of course, a chamber cast is good, and getting a gunsmith to look it over before you fire it is a wonderful idea, but it's easy to get an idea of chamber length without going to a gunsmith.