I know they use ceramic in high end brake systems for supercars because of the heat-handling properties
The true, "high end" vehicles are running carbon-ceramic rotors. It is said to make a substantial difference in braking ability. (The weight loss doesn't hurt.) However, they still have to be a carbon composite, and are attached to a metal rotor. If the carbon-ceramic plates were not reinforced by the inner metal rotor, they would shatter on the first use.
To make a little money off the concept....
Nearly every vehicle in current production is running "ceramic" brake pads. How much does it affect the average vehicle's braking ability? Zero. There isn't enough of the ceramic material in the brake pad composite, and brake pads don't do anything for cooling, anyway. But... In the good systems (Lincoln, Cadillac, Mercedes, BMW, etc), there is a noticeable difference in the performance of ABS and traction control systems. Friction.
The down side of those "good" systems, is increased wear on the rotors. As the ceramic content in the brake pad composite is increased, the rate at which the rotors wear increases, as well.
How is this firearms related?
One simple statement: There's no free lunch, with current technology.