You would think with all the blackpowder cartridge shooters that someone would have come out with 45 LC cases that are close to the balloon head in powder capacity.
I found one, don't remember where I got it, but I found it as it did not have an extractor groove in the case. It would not go into the Dillion shell holder. Looking inside it, the primer pocket was exposed, and that is the only balloon head I have ever handled. I loaded 8.5 grains Unique with a 250 and it worked fine, but I retired the case because it is a historical curiosity.
Yes they would be weaker than solid head and not appropriate for smokeless, but they should be just fine for blackpowder.
I gave away my Lyman Blackpowder handbook, but blackpowder pressures were in lead units because copper is too hard. If Civil War musket barrels were made from wrought iron, with pressures below 6000 lead units, a balloon head case should be just fine with blackpowder pressures.
And I would like to see if I can get 1000 fps with a 250 L at blackpowder pressures in a 45 LC.
I did try using FFG in solid head cases, I did not know you were supposed to use a different lube, and that experience was so bad I have not tried it again. Wish I had chronograph data because I am curious what velocities I could get with a modern solid head case.