454 cylinder expansion
I gather you're using factory ammo, which should fire well within standard operating pressures. I've heard about this problem with 454 Casull in the Super Redhawk. The "official" explanation offered is that the cylinder steel is quite elastic - more than usual. When the round is fired, the cylinder expands (stretches) allowing the case to expand with it. Hence, when the cylinder rebounds back to normal size, it clamps onto the less elastic case causing sticking. My 454 Super Redhawk doesn't have this problem - in fact, I fire hot reloads (i.e., 32.5 grs. of WW296 behind a 300 gr. Nosler partition) without any sticking at all. This is a wrist-breaking load (~1700 fps), which I plan to reduce.